There is only one alignment value that is changed during alignment on the front end. That would be the TOE...it's either in or out...
The other alignment values are set by the condition of the bushings in your control arms.
Other factors come into play as worn tie rod ends that won't allow a toe angle to be set.
The rear is affected the same as the front except there is no adjustment. However, the alignment will show if there are bushings that are out of spec.